Volatiles at the Lunar South Pole: mission to  AMUNDSEN CRATER

The Amundsen crater is centered at 84.6°South, 85.6°East. Its diameter is about 100-km in the form of a complex crater, with heavily terraced walls and prominent central peaks.

Amundsen has been formed in the late Nectarian (~3.92–3.85 Ga), though its floor is somewhat younger (Imbrian, ~3.85–3.8 Ga). The crater floor has relatively low slopes (< 5º), which are attractive for landing and rover operations. Amundsen sits on the southern limb of the South Pole-Aitken (SPA) basin (D ~ 2500 km), the oldest and largest discernible impact crater on the lunar surface.
Because of the great depth of the SPA at about 13 km, its mineralogy is likely intermediate between mafic and felsic, because the mixing of lower crustal or upper mantle material with feldspathic highlands material.
It contains a broad range of geologic units, such as impact melts or volcanic material on the crater floor, bedrock outcrops on its wall, slumped material from high on the crater’s rim, and uplifted basement rocks in the central peak. On its floor, we can find many small (km-scale) craters in various states of degradation .

LUNAR SOUTH POLE

Above: spectacular oblique view of the rim of Shackleton crater (21 km diameter, 89.66°S, 129.20°E). While no location on the Moon stays continuously illuminated, three points on the rim remain collectively sunlit for more than 90% of the year. These points are surrounded by topographic depressions that never receive sunlight, creating cold traps that can capture ices, NAC M1224655261LR [NASA/GSFC/Arizona State University].

The spin axis of the Moon is titled less than two degrees, thus the lighting conditions at the poles are always extreme. The long deep shadows give the impression that the polar regions are unusually rough and thus dangerous. However, the topography is no different than that found near the equator. So, polar landings should be relatively safe, even in permanently shadowed regions (PSRs), if the spacecraft is equipped with active landing sensors (lidar or radar). The permanent shadows are formed by topographic highs, and even though these high points are often narrow, they are very inviting landing spots because many are illuminated for most of the lunar year. Future surface missions to the lunar poles will likely utilize these highly illuminated regions, where solar power is abundant, as jumping off points to determine what volatiles (water ice, methane, etc.) PSRs may hold, and how these volatiles can be utilized as resources for future human exploration. For now, you can explore the high-resolution oblique view of the illuminated rim of Shackleton crater near the South Pole, on the right.

On the left: Spectacular oblique view of the rim of Shackleton crater (21 km diameter, 89.66°S, 129.20°E). While no location on the Moon stays continuously illuminated, three points on the rim remain collectively sunlit for more than 90% of the year. These points are surrounded by topographic depressions that never receive sunlight, creating cold traps that can capture ices, NAC M1224655261LR [NASA/GSFC/Arizona State University].

Rovers and instruments that could explore these regions would normally rely on solar power and batteries for power. Even in places near the poles that receive some sunlight, it is necessary to understand how much sunlight they receive so that a rover does not accidentally become stuck in the dark long enough to run down its batteries.

The South polar region has ~46% more sites than the North. Its almost 4,000 km2 more coverage permit it to reach Science Goals targeted. This is the reason why, the south polar region is preferred.

The above illustration show an enhanced view of recommended sites in the South Polar region satisfying Science Goal 4c: Understant the transport, retention, alteration, and loss processes that operate on volatile materials at Permanetly Shaded Lunar Regions.

Amundsen is a particularly attractive landing site due to its sizeable Permanently Shadowed Regions (PSRs), which may thermally trap volatiles, and its relatively high hydrogen abundances (~100 to ~150 ppm) set amongst diverse geologic units. 
Moreover, one mission can land on a relatively flat crater floor in the sunlight, where solar power is available, and then make brief traverses into shadowed regions. 
The study of Runyon & Al. identified two landing sites (A and B) on the floor of Amundsen crater that are lit up to ~25% of a lunation.  Those sites provide access to stations within PSRs while providing a base of operations in an illuminated region.  Having the ability to establish stations in both sunlit regions and adjacent PSRs has several scientific advantages. 
The stations outside of PSRs can serve as experimental controls for the processes that affect volatile distribution within PSRs.  Contrasts between the two regions can also be used to evaluate transport mechanisms.  Remotely observed circular polarization ratios (CPR) also vary around both landing sites, providing an opportunity to groundtruth the global data set and test the effects of ground ice and surface roughness on those CPR values. Temperatures derived from the Diviner radiometer also helped define station locations. 

 

 
 

 The Permanently Shadowed Regions (PSRs) in the South Pole and the longitude/latitude grid. Credit: lroc.asu.edu/NASA 

The Area A is located at 83.93°S and 90.45°E with six science stations. All have elevated in hydrogen levels, ~110– 123 ppm, less than 15° of navigable slopes, and temperatures ranging from ~23–100 K, with an average of about 40–50 K.
Stations A1 and A6 address three of the five NRC science goals(b, c, and e), while A2 to A5 address them all.
The maximum temperature (Tmax) distribution places constraints on stations’ expected volatile abundance based on volatiles’ sublimation points.
Volatile sublimation temperatures near the Tmax of the stations include CO2 and hydrogen sulfide for Stations A2 to A5. For the Station A1, it include water and ammonium hydrosulfide and, we have toluene  at the Station A6.
These stations explore the distribution of volatiles in several geologic sites that will have variable regolith properties and potentially cavities for icy deposits.
The Station A1 is in a small PSR amidst an interesting complex of overlapping, asymmetric simple craters. A2 is on a flat terrain, while A3 and A4 are on degraded crater rims, though the latter is also near fresh craters and their ejecta. The A5’s location is on a debris slump that will allow sampling of a range of lithologies, particularly from higher on Amundsen’s wall and rim. Finally, A6 is on the terraced wall.
All but Station A6 are within the 10 km astronaut walk-back safety zone. 

TheAmundsen crater, showing PSRs (dark blue), sites where all five science goals can be met simultaneously (light blue), proposed science stations (circles), and proposed landing sites (stars). Radii of 10 and 20 km from the landing sites shown as solid & dashed lines. Base map is LRO/WAC/LOLA shaded relief.

The Area B  is located at 83.82°S and 87.53°E with seven science stations. All have elevated hydrogen levels, between ~98–125 ppm, slopes less than 6°, and temperatures ranging from ~23–239 K, with an average of ~37–73 K.
Stations B1 and B2 address none of the science goals directly but serve as controls.  Stations B3, B6, and B7 address all five of the NRC goals, while stations B4 and B5 address goals b, c, and e.
Area B also allows sampling in various geologic regimes. Station B1 is in a diurnal region at the base of Amundsen’s central peak. B2 is in a small PSR on the bottom of a small, fresh crater while B3 is on the flat Amundsen floor very near the terraced walls. Stations B4 and B5 are on different debris slumps, allowing for sampling of stratigraphically higher and laterally diverse material. B6 samples a simple crater on Amundsen’s terrace. Station B7 also samples the terrace, though in a location that also satisfies all five NRC goals.
The Amundsen crater is a prime area for studying lunar volatiles. Its geologic diversity, elevated hydrogen  abundances, cold PSRs adjacent to warmer diurnal regions, and overall accessibility make it an appealing and interesting target for future lunar missions from both science and mission planning perspectives.
This is in contrast to the more limited science opportunities at Shackleton crater, which has steeper walls, simpler geology, and whose interior is entirely in permanent shadow.

GENERAL MOON FACTS

Average Distance from Earth: 238,855 | 384,400 kilometers
Orbit and Rotation Period: 27.32 Earth Days
Equatorial Radius: 1,079.6 miles | 1.737.5 kilometers
Mass: 0.0123 of Earth's (a bit more than 1 percent)
Gravity: 0.166 of Earth's (If you weigh 100 pounds (45 kilograms) on Earth, you'd weight 16.6 pounds (7.5 kilograms) on the moon)
Temperature Range: -414 to 253 degrees Farenheit (-248 to 123 degrees Celsius)
The moon’s iron-rich inner  is about 149 miles, or 240 km, in radius. It is surrounded by a liquid iron shell of 56 miles (90 km) thick, and a partially 93 miles (150 km) molten layer of a thickness.
The mantle extends from the top of the partially molten layer to the bottom of the moon’s crust. It is most likely made of minerals like olivine and pyroxene, which are made up of magnesium, iron, silicon and oxygen atoms.
The crust has a thickness of about 43 miles (70 km) on the near-side hemisphere and 93 miles (150 km) on the far-side. It is made of oxygen, silicon, magnesium, iron, calcium and aluminum, with small amounts of titanium, uranium, thorium, potassium and hydrogen.

The region poleward of 80°S is almost entirely within the South Pole-Aitken (SPA) basin, the largest and oldest discernible impact basin on the Moon. The study area is dominated by heavily degraded impact craters ~20–100 km in diameter. The large craters are mostly flat-floored, with the exception of two craters that exhibit central peaks. Fresh, bowl-shaped craters are rare, although Shackleton is a prime example of a crater of this type. The terrain at the South Pole is mostly pre-Nectrain basin and crater material, but also includes some Nectarian and Orientale basin materials (USGS, 2009a).

In the South pole, sites of interest are located above the 84° latitude. In this region, the largest site is on the northeastern part of the floor of the Amundsen crater. Within the smaller craters in Faustini, Haworth, and de Gerlache craters, small sites are concentrated in an elevated area between Haworth and Nobile craters.

The Amundsen crater could be an excellent choice of landing because their sites are within a PSR and is surrounded by warmer regions that are mostly illuminates. With a Central Peak and walls that have slopes shallower than 25°, it allow easy exploration.
In the South pole regions showing below, a small concentration of sites are visible mostly on the floors of medium-to-large craters. Those craters are Amundsen, Faustini, Haworth, and de Gerlache craters, as well as the plains west of Shoemaker. 

The highest priority for landing sites is to have a maximum annual temperature of ≤54 K , usually within PSRs.  At this point, it will be possible to study physical properties of the extremely cold regolith.
A mission needs to access areas where the NRC’s science goals can be  addressed. These goals are (1) to determine the compositional state and distribution of volatiles in lunar polar regions, (2) to determine the sources for lunar polar volatiles, (3) to understand the transport, retention, alteration, and loss processes that operate on volatile materials at PSRs, (4) to understand the physical properties of the extremely cold polar regolith, and (5) to determine what the cold polar regolith reveals about the ancient solar environment .
From these criteria, the research has been limited to sites with temperatures of 54–130 K (below the sublimation point of various volatiles) and where slopes and the local geology reach NRC's goals. Thus, the focus of any measurements will be on the 9% of the Amundsen’s interior that is in permanent shadow.

Collection of a rake sample on the Apollo 16 mission (Apollo 16 photograph AS16–116–18690). Credit: NASA

*K. D. Runyon and al. - 43rd Lunar and Planetary Science Conference (2012) PDF1619

Reference: A Global Lunar Landing Site Study to Provide the Scientific Context for Exploration of the Moon / Edited by David A. Kring and Daniel D. Durda / Study Prepared by Members of the LPI-JSC Lunar Exploration Summer Intern Program / LPI-JSC Center for Lunar Science and Exploration / A Member of the NASA Lunar Science Institute / Copyright  2012 / LPI Contribution No. 1694
Many sites also can address Science Goal 4e in the south polar region. The figure below shows a close-up view of the recommended landing sites there, found in large craters such as Cabeus, Cabeus B, Amundsen, Idel'son, Shoemaker, Haworth, and Nobile as well as in smaller craters such as Faustini, Wiechert, Wiechert U, Wiechert P, Sverdrup, de Gerlache, and on the floor of Skackleton.

 

Apollo 14 was the eighth manned mission in the Apollo programme and the third mission to land on the Moon, touching down on 5 February 1971. The crew were Commander Alan B. Shepard, Jr, Stuart A. Roosa (Command Module Pilot) and Edgar D. Mitchell (Lunar Module Pilot). After landing at the destination for Apollo 13 - Shepard and Mitchell took two moon walks, adding new seismic studies to the by now familiar Apollo experiment package, and using a "lunar rickshaw" pull cart to carry their equipment...

There are very few sites where all goals overlap in the North Polar Region, as seen into the above image. Generally, these are patchy areas related to degraded crater morphologies, particularly in the Intercrater Polar Highlands (IPH) near the geographic North Pole. The largest continuous region of Science Goal overlap is in Lenard crater (D = 48 km). Other notable areas include sites on the floor of Peary crater, and on the southern walls of Rozhdestvenskiy W, Hermite, and Peary craters. There are more areas on the North Pole than at the South Pole that can address all five Science Goals simultaneously.

In the South Polar Region, many sites can be found in the bottoms of smaller craters within larger craters. This is the case for Faustini, de Gerlache, Haworth, Shoemaker, and some of the Near-Polar Highlands/Intercrater Areas. The largest Science Goal overlap site at the South Pole is Amundsen crater (D = 105 km), which is also a convenient site because there are a range of morphologies present on the crater floor, allowing contrasting areas with different physical or thermal properties.
The coldest temperatures measured on the Moon are below 23 K (Paige et al., 2011), which puts them in the same temperature range as the stability of xenon (Xe), krypton (Kr), and argon (Ar) (Zhang et al., 2010). This means that there is a possibility that noble gases could be frozen out of the lunar exosphere in these places and possibly sequestered in the regolith, at least for short periods of time. Because the lowest average temperatures on the Moon are around 38 K (Paige et al., 2011), long-term solid-state storage of noble gases seems unlikely, but periodic „trap-and-release‟ cycles may be more common. This provides an interesting analog for periodic comets, which may undergo similar temperature fluctuations as they change distance from the Sun.

Enhanced view of recommended sites in the south polar region satisfying Science Goal 4e.
Science Goal 4a: Determine the compositional state (elemental, isotopic, mineralogic) and compositional distribution (lateral and depth) of the volatile component in lunar polar regions.

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